1 Introduction
Scent from a buried source moves through the soil, ground cover, scent boundary layer, and into the air where it can be detected (Figure 1). The availability of scent in the air above a buried source depends on the properties of the soil and scent molecules and their interactions; on processes that occur in the soil, ground cover, and scent boundary layer; and on the weather. Scent plume movement in air is influenced by terrain and vegetation, and weather influences scent movement through all media between the source and the dog. Scent movement through the soil is constrained because it can move only in the pore spaces between soil particles while in the gas and liquid phases. Scent transport also depends on the rate of movement and on whether the VOCs are in the gas phase or the water phase (i.e. how they are distributed or partitioned between phases). In dry soil, VOCs are adsorbed on the soil particle surfaces as a kind of residue and are not free to move. Our primary interest is in upward movement of scent, but downward movement can be of interest especially in the presence of flowing underground water.